Inorganic Chemistry. Part I
Inorganic chemistry is the branch
of chemistry concerned with the properties and behavior of inorganic
compounds. This field covers all chemical compounds except the myriad
organic compounds (compounds containing C-H bonds), which are the subjects
of organic chemistry. The distinction between the two disciplines is far
from absolute, and there is much overlap, most importantly in the
sub-discipline of organometallic
The bulk of inorganic compounds occur as salts, the combination of cations
and anions joined by ionic bonding. Examples of cations are sodium Na+, and
magnesium Mg2+ and examples of anions are oxide O2− and chloride Cl−. As
salts are neutrally charged, these ions form compounds such as sodium oxide
Na2O or magnesium chloride MgCl2. The ions are described by their oxidation
state and their ease of formation can be inferred from the ionization
potential (for cations) or from the electron affinity (anions) of the parent
elements.
Important classes of inorganic compounds are the oxides, the carbonates, the
sulfates and the halides. Many inorganic compounds are characterized by high
melting points. Inorganic salts typically are poor conductors in the solid
state. Another important feature is their solubility in e.g. water (see:
solubility chart), and ease of crystallization. Where some salts (e.g. NaCl)
are very soluble in water, others (e.g. SiO2) are not.
The simplest inorganic reaction is double displacement when in mixing of two
salts the ions are swapped without a change in oxidation state. In redox
reactions one reactant, the oxidant, lowers its oxidation state and another
reactant, the reductant, has its oxidation state increased. The net result
is an exchange of electrons. Electron exchange can occur indirectly as well,
e.g. in batteries, a key concept in electrochemistry.